Business & Products

H₂ Separation and Purification

SWCHEM’s PSA-H₂ technology separates and purifies H₂ from H₂-containing gas streams by taking advantage of the different adsorption capacities of adsorbents for various gas components under different pressures.

Under elevated pressure, impurities in the feed gas are selectively adsorbed by the adsorbent, while weakly adsorbed components such as H₂ pass through the adsorber as product gas. When the pressure is reduced, the adsorbed impurities are desorbed and the adsorbent is regenerated.

The process is operated in cycles with multiple adsorbers working alternately, enabling continuous production of H₂.

Process principle

The PSA-H₂ process is based on selective adsorption and pressure swing regeneration.

At higher pressure, impurities such as CO, CO₂, CH₄, N₂ and other components are adsorbed on the adsorbent bed. H₂, as a weakly adsorbed component, passes through the adsorber and is collected as product gas.

During regeneration, the adsorber pressure is reduced, allowing the adsorbed impurities to be released. The regenerated adsorber is then repressurized and returned to the adsorption step.

Typically, at least four adsorbers are required for alternating operation to ensure continuous product gas output.

Feed gas

Applicable feed gases include:

  • Methanol decomposition gas, ammonia decomposition gas, methanol tail gas and formaldehyde tail gas
  • Shift gas, refinery gas, fermentation gas and polycrystalline silicon tail gas
  • Semi-water gas, city gas and coke oven gas
  • Catalytic cracking gas and reformer tail gas from oil refineries
  • Other H₂-containing gas streams

Technical data

Feed gas:

ItemData
Pressure0.4–7.0 MPa(g)
TemperatureAmbient temperature

Product gas: H2

ItemData
ProductH₂
H₂ purity98.5–99.999 vol%, adjustable according to customer requirements
H₂ recovery80–99%
System pressure drop, ΔP0.05–0.1 MPa
TemperatureAmbient temperature

Note: H₂ recovery depends on feed gas composition, feed pressure, required product H₂ purity and trace impurity requirements.

Control Mode and Features

Control Mode

PSA units are controlled by dedicated controllers and instruments. Depending on the PSA unit capacity, automation level and customer control requirements, a DCS control system consistent with the customer’s main plant may be used, or a standalone PLC control system may be selected.

Control Features

In addition to conventional PSA sequence control, loop control and other control functions, SWCHEM also provides specialized control strategies for fully automatic load adjustment, fault diagnosis and fault isolation.

The system can support adaptive optimization, self-diagnosis and fault isolation, improving operational flexibility and helping ensure long-term, stable and safe operation of the unit.

Service Scope

SWCHEM provides:

  • Proprietary and patented PSA-H₂ technology
  • Dedicated PSA-H₂ adsorbents and program-controlled valves
  • Process design and engineering design
  • EPC project delivery
  • Technical services and staff training during installation and commissioning
  • One-year warranty period after inspection and acceptance
  • Long-term supply of spare parts and accessories
  • Remote online diagnostics and services (optional)

Typical Reference

50,000 Nm³/h PSA-H₂ Unit from Reforming Gas
280,000 Nm³/h PSA-H₂ Unit for Direct Coal-to-Oil
170,000 Nm³/h PSA-H₂ Unit for Indirect Coal to Oil
220,000 Nm³/h PSA-H₂ Unit from Reforming Gas in Brunei
480,000 Nm³/h PSA-H₂ Unit for the World’s Largest Coal-to-Ethylene Glycol Project
Produced By CMS 网站群内容管理系统 publishdate:2026-09-28 10:19:05